Product ID:EASTMAN MPK (METHYL PROPYL KETONE)
MSDS Date:06/18/1999
FSC:6810
NIIN:01-459-1990
Status Code:A
MSDS Number: CJKXL

EASTMAN CHEM PRODUCTS A SUB OF EASTMAN KODAK CO

WILCOX DR AND LINCOLN ST
KINGSPORT, TN 37662
US

Emergency Phone: 1-800-EASTMAN

Info Phone: 615-229-6094/2000

Cage: 74364

TELECHEM INTERNATIONAL, INC

SUNNYVALE, CA 94089-2115 US

Telephone: 916-941-3688

Cage: 1KH20

METHYL PROPYL KETONE

CAS: 107-87-9

RTECS: SA7875000

OSHA PEL 700 MG/M3;200 PPM

ACGIH TLV: 705 MG/M3;200 PPM

METHYL ISOBUTYL KETONE

CAS: 108-10-1

RTECS: SA9275000

OSHA PEL 410 MG/M3;100 PPM

ACGIH TLV: 205 MG/M3;50 PPM

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

LD50 LC50 Mixture:LD50 (ORAL, RAT) 3.73 G/KG
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:GENERAL: BASED ON ANIMAL DATA AND
STRUCTURE-ACTIVITY RELATIONSHIPS, THIS PRODUCT IS NOT EXPECTED TO
CAUSE NERVOUS SYSTEM DAMAGE. INHALATION: HIGH VAPOR
CONCENTRATIONS MAY CAUSE DROWSINESS AND IRRIT ATION. EYES: HIGH
VAPOR CONCENTRATIONSMAY CAUSE IRRITATION. SKIN : EXPECTED TO BE A
LOW HAZARD FOR USUAL INDUSTRIAL OR COMMERCIAL HANDLING BY TRAINED
PERSONNEL. INGESTION: EXPECTED TO BE A LOW INGES TION HAZARD.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:INHALATION: HIGH VAPOR CONCENTRATIONS MAY
CAUSE DROWSINESS AND IRRITATION. ` EYES: HIGH VAPOR CONCENTRATIONS
MAY CAUSE IRRITATION.

First Aid:INHALATION: MOVE TO FRESH AIR. TREAT SYMPTOMATICALLY. GET
MEDICAL ATTENTION IF SYMPTOMS PERSIST. EYES: IN CASE OF IRRITATION
FROM AIRBORNE EXPOSURE, MOVE TO FRESH AIR. IF EASY TO DO, REMOVE
CONTACT L ENSES. GET MEDICAL ATTENTION IF SYMPTOMSPERSIST. SKIN:
WASH WITH SOAP AND WATER. GET MEDICAL ATTENTION IF SYMPTOMS OCCUR.
INGESTION: SEEK MEDICAL ADVICE.

Flash Point Method:TCC
Flash Point:=7.8C, 46.F
Autoignition Temp:=448.9C, 840.F
Lower Limits:(93F):1.56%
Upper Limits:(144F):8.7%
Extinguishing Media:WATER SPRAY, DRY CHEMICAL, CARBON DIOXIDE (CO2),
ALCOHOL FOAM
Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS AND
PROTECTIVE CLOTHING. USE WATER SPRAY TO KEEP FIRE-EXPOSED
CONTAINERS COOL. WATER MAY BE INEFFECTIVE IN FIGHTING THE FIRE.
Unusual Fire/Explosion Hazard:FLAMMABLE. VAPORS MAY CAUSE A FLASH FIRE
OR IGNITE EXPLOSIVELY. VAPORS MAY TRAVEL CONSIDERABLE DISTANCE TO A
SOURCE OF IGNITION AND FLASH BACK. PREVENT BUILDING OF VAPORS OR
GASES TO EXPLOSIVE CONC ENTRATIONS.

Spill Release Procedures:USE PERSONAL PROTECTIVE EQUIPMENT. ELIMINATESE
ALL IGNITION SOURCES. ABSORB SPILL WITH VERMICULITE OR OTHER INERT
MATERIAL, THEN PLACE IN A CONTAINER FOR CHEMICAL WASTE. FOR LARGE
SPILLS: USE WATER SP RAY TO DISPERSE VAPORS AND DILUTE SPILLTO A
NONFLAMMABLE MIXTURE. PREVENT RUNOFF FROM ENTERING DRAINS, SEWERS,
OR STREAMS.

Handling and Storage Precautions:KEEP CONTAINER TIGHTLY CLOSED. KEEP
CONTAINER IN A WELL-VENTILATED PLACE. KEEP AWAY FROM HEAT, SPARKS,
AND FLAME. KEEP FROM CONTACT WITH OXIDIZING MATERIALS. USE ONLY
WITH ADEQUATE VENTILATION. COMPLY WITH ALL NATIONAL, STATE, AND
LOCAL CODES PERTAINING TO STORAGE AND HANDLING OF FLAMMABLE
LIQUIDS.
Other Precautions:AVOID BREATHING HIGH VAPOR CONCENTRATIONS. USE ONLY
WITH ADEQUATE VENTILATION.

Respiratory Protection:IF ENGINEERING CONTROLS DO NOT MAINTAIN AIRBORNE
CONCENTRATIONS BELOW RECOMMENDED EXPOSURE LIMITS, AN APPROVED
RESPIRATOR MUST BE WORN: RESPIRATOR TYPE: ORGANIC VAPOR. IF
RESPIRATORS ARE USED, A PROG RAM SHOULD BE INSTITUTED TO ASSURE
COMPLIANCE WITH OSHA STANDARD 63 FR 1152, JAN 8, 1998.
Ventilation:GOOD GENERAL VENTILATION (TYPICALLY 10 AIR CHANGES PER
HOUR) SHOULD BE USED. USE PROCESS ENCLOSURES, LOCAL EXHAUST
VENTILATION OR OTHER CONTROLS.
Protective Gloves:IT IS A GOOD INDUSTRIAL HYGIENE PRACTICE TO MINIMIZE
SKIN CONTACT.
Eye Protection:IT IS A GOOD INDUSTRIAL HYGIENE PRACTICE TO MINIMIZE EYE
CONTACT.
Other Protective Equipment:EYE BATH, WASHING FACILITIES.
Supplemental Safety and Health
PRODUCT ID NUMBER: SPC 19010. SINCE EMPTIED CONTAINERS RETAIN
PRODUCT RESIDUE, FOLLOW LABEL WARNINGS EVEN AFTER CONTAINER IS
EMPTIED. RESIDUAL VAPORS MAY EXPLODE ON IGNITION; DO NOT CUT,
DRILL GRI ND, OR WELD ON OR NEAR THIS CONTAINER.

HCC:F2
Boiling Pt:=100.6C, 213.F
Melt/Freeze Pt:=-77.8C, -108.F
Vapor Pres:AT20C (68F)37BAR(27.8MMHG
Vapor Density:(AIR=1)2.9
Spec Gravity:AT 20C (68F)(H20=1):0.81
Evaporation Rate & Reference:(N-BUTYL ACETATE=1):2.3
Solubility in Water:MODERATE
Appearance and Odor:COLORLESS LIQUID - KETONE ODOR

Stability Indicator/Materials to Avoid:YES
MATERIAL CAN REACT VIOLENTLY WITH STRONG BASES, STRONG OXIDIZING
AGENTS, STRONG REDUCING AGENTS.
Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE
Conditions to Avoid Polymerization:WILL NOT OCCUR.

Waste Disposal Methods:DISCHARGE, TREATMENT, OR DISPOSAL MAY BE SUBJECT
TO NATIONAL, STATE, OR LOCAL LAWS. MIX WITH COMPATIBLE CHEMICAL
WHICH IS LESS FALMMABLE AND INCINERATE. SINCE EMPTIED CONTAINERS
RETAIN PRODUCT RESIDUE , FOLLOW LABEL WARNINGS EVEN AFTER CONTAINER
IS EMPTIED. RESIDUAL VAPORS MAY EXPLODE ON IGNITION; DO NOT CUT,
DRILL, GRIND/WELD ON OR NEAR CONTAINER.

Toxicological Information:INHALATION LC-50 (RAT): >2000 PPM/4 HOURS.
DERMAL LD-50 (RABBIT): 8 ML/KG. SKIN IRRITATION (GUINEA PIG): 8
ML/KG. REPEATED SKIN IRRITATION (GUINEA PIG): SLIGHT IRRITATION.
EYE IRRITATION (RABBIT): SLI GHT. SUBCHRONIC TOXICITY DATA FOR
METHYL PROPYL KETONE: NO-OBSERVED-EFFECT LEVEL (NOEL) FOR
NEUROTOXICITY = 305 PPM (ONLY CONCENTRATION TESTED). ORAL STUDY (10
MONTHS, RAT): LOWEST-OBSERVED-EFFECT LEV EL (LOEL) = 1% IN DRINKING
WATER (REDUCED BODY WEIGHT GAIN); NOEL = 0.5% IN DRINKING WATER.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ecological:IT HAS THE FOLLOWING PROPERTIES: A HIGH BIOCHEMICAL OXYGEN
DEMAND AND A POTENTIAL TO CAUSE OXYGEN DEPLETION IN AQUEOUS
SYSTEMS, A LOW POTENTIAL TO AFFECT AQUATIC ORGANISMS, A HIGH
POTENTIAL TO BIODEGR ADE (LOW PERSISTANCE) WITH
UNACCLIMATEDMICROORGANISMS FROM ACTIVATED SLUDGE. WHEN DILUTED WITH
A LARGE AMOUNT OF WATER, THIS MATERIAL RELEASED DIRECTLY OR
INDIRECTLY INTO THE ENVIRONMENT IS NOT EXPECT ED TO HAVE A
SIGNIFICANT IMPACT. OXYGEN DEMAND DATA: THOD=2.6 G OXYGEN/G.
COD=1.8 G OXYGEN/G. BOD-5=1.38 G OXYGEN/G. BOD-20=1.8 G OXYGEN/G.

Transport Information:DOT (USA) STATUS: REGULATED. CLASS 3, PACKING
GROUP II. IAR (INTERNATIONAL CIVIL AVIATION ORGANIZATION) ICAO.
ICAO STATUS: REGULATED. CLASS 3, PACKING GROUP II. SEA-
INTERNATIONAL MARITIME DANGEROUS G OODS (IMDG). IMDG STATUS:
REGULATED. CLASS 3.2, PACKING GROUP II.

SARA Title III Information:CHEMICALS SUBJECT TO THE REPORTING
REQUIREMENTS OF SECTION 313 OF TITLE III OF THE SUPERFUND
AMENDMENTS AND REAUTHORIZATION ACT (SARA) OF 1986 AND 40 CFR PART
372: METHYL ISOBUTYL KETONE. SARA (U.S.A .) SECTION 311 AND 312
HAZARD CLASSIFICATION: FIRE HAZARD, IMMEIDATE (ACUTE) HEALTH
HAZARD.
Federal Regulatory Information:US TOXIC SUBSTANCE CONTROL ACT (TSCA):
ALL COMPONENTS OF THIS PRODUCT ARE LISTED ON THE TOXIC SUBSTANCE
CONTROL ACT (TSCA) INVENTORY. ANY IMPURITIES PRESENT IN THIS
PRODUCT ARE EXEMPT FROM LISTING.
State Regulatory Information:CA PROPOSITION PROPOSITION 65: NONE KNOWN
TO EASTMAN.